By Edward V. Thompson (auth.), Daniel Klempner, Kurt C. Frisch (eds.)
ISBN-10: 1468436295
ISBN-13: 9781468436297
ISBN-10: 1468436317
ISBN-13: 9781468436310
The time period "alloy" as bearing on polymers has develop into an more and more renowned description of composites of polymers, parti cularly because the ebook of the 1st quantity during this sequence in 1977. Polymer alloy refers to that category of macromolecular fabrics which, often, involves mixtures of chemically various polymers. The polymers excited about those combos should be hetero geneous (multiphase) or homogeneous (single phase). they're associated including covalent bonds among the part polymers (block copolymers, graft copolymers), associated topologically without covalent bonds (interpenetrating polymer networks), or now not associated in any respect other than bodily (polyblends). moreover, they're linear (thermoplastic), crosslinked (thermosetting), crystalline, or amorphous, even though the latter is extra universal. To the massive pride - yet now not shock - of the editors, there was no lessen within the examine and improvement of polymer alloys because the e-book of the 1st quantity, as evidenced through a variety of courses, meetings and symposia. persisted advances in polymer know-how attributable to the layout of recent kinds of polymer alloys have additionally been famous. This technolog ical curiosity stems from the truth that those fabrics quite often convey a synergism in homes a possibility purely by means of the formation of polymer alloys. The vintage examples, after all, are the excessive impression plastics, that are both polyblends, block, or graft co polymers composed of a rubbery and a glassy polymer. Interpene trating polymer networks (IPN's) of such polymers additionally express an identical, or maybe larger, synergism.
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Additional resources for Polymer Alloys II: Blends, Blocks, Grafts, and Interpenetrating Networks
Sample text
22. Regions of three types of phase relationships observed in the PS/P(25MMA-75S) system. 22 EDWARD V. THOMPSON system, and therefore seems to us to justify their use in the following discussions. Phase Relationships There have been relatively few systematic investigations of the phase relationships of polymer/polymer/solvent systems, and of these we note in particular the studies of: Dobry and BoyerKawenoki (2) (polystyrene/polybutadiene/benzene), perhaps the first report to appear describing the phase diagram of a polymer/polymer/ solvent system; Kern and Slocombe (40) (a variety of vinyl polymers); and Paxton (41) (polystyrene/polybutadiene/toluene).
23 POLYSTYRENE IN POLY (METHYL METHACRYI:ATE) (methyl methacrylate-styrene) copolymer/nlethyl methacrylate-styrene comonomer (hereafter denoted PS/P(MMA-S)/MMA-S) systems have not, to our knowledge, been worked out, particularly as a function of molecular weight of PS and P(MMA-S) composition. Nevertheless, based on the properties of similar systems, we assume phase diagrams and dependences on molecular weight of PS and P(MMA-S) composition as shown in Figures 24 and 25, respectively, where we note the following points: 1.
19. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. 31. 32. 33. 34. 35. 36. 37. 38. 39. 40. 41. 42. 39 R. N. Haward and I. Brough, Polymer, 10:724 (1969). H. Keskku1a, App1. Po1ym. , 15:51 (1970). R. J. Williams and R. W. A. Hudson, Polymer, 8:643 (1967). C. B. Buckna11 and R. R. Smith, Polymer, 6:437 (1965). M. Matsuo, Po1ym. Eng. , 9:206 (1969). M. Baer, J. App1. Po1ym. , 16:1109 (1972). J. D. Moore, Polymer, 12:478 (1971). G. E. Mo1au, J. Po1ym. , Part A, 3:1267 (1965). , 4235. G. E. Mo1au, J. Po1ym.
Polymer Alloys II: Blends, Blocks, Grafts, and Interpenetrating Networks by Edward V. Thompson (auth.), Daniel Klempner, Kurt C. Frisch (eds.)
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