By Christopher D. Rahn
Chapter 1 creation (pages 1–10):
Chapter 2 Electrochemistry (pages 11–22):
Chapter three Governing Equations (pages 23–48):
Chapter four Discretization equipment (pages 49–87):
Chapter five method reaction (pages 89–118):
Chapter 6 Battery approach types (pages 119–160):
Chapter 7 Estimation (pages 161–189):
Chapter eight Battery administration structures (pages 191–229):
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Content material: bankruptcy 1 advent (pages 1–10): bankruptcy 2 Electrochemistry (pages 11–22): bankruptcy three Governing Equations (pages 23–48): bankruptcy four Discretization equipment (pages 49–87): bankruptcy five method reaction (pages 89–118): bankruptcy 6 Battery approach types (pages 119–160): bankruptcy 7 Estimation (pages 161–189): bankruptcy eight Battery administration platforms (pages 191–229):
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Extra resources for Battery Systems Engineering
This layer is beneﬁcial and essential for proper cell operation, but an electrolyte reduction side reaction can occur that causes aging. , ethylene carbonate) reacts to increase the thickness of the SEI layer due to product precipitation. A surface ﬁlm on the active particles also occurs in the cathode. The ﬁlm thickness does not change signiﬁcantly during aging, but its porosity, conductivity, and diffusion coefﬁcient do change over time due to precipitate of side-reaction product that blocks the pores of the existing surface ﬁlm.
7) + The HSO− 4 and H ions come from dissolved H2 SO4 . The acid is consumed in both the positive and negative electrodes during discharge. The H+ ions produced in the negative Governing Equations 25 electrode migrate to the positive electrode. 8) of H2 SO4 is consumed at each electrode. This example shows the need to balance the various species in a cell to maximize energy storage. Acid, Pb, and PbO2 are all consumed during discharge but at different rates. For maximum energy storage, all three active materials should be expended at the same time.
The ions originate in one insertion electrode, travel through the electrolyte, and intercalate in the other insertion electrode. Electrons enter or leave the crystal to maintain electroneutrality and produce the desired current ﬂow. 1 Ion Transport Transport in the electrolyte phase of batteries involves the movement of charged species (ions) across the cell and the corresponding changes in ionic concentration distribution c(x, t) that depend on the position in the cell x and time t. Ni–MH and Li-ion batteries have one kind of charged species that travels through the unary electrolyte.
Battery Systems Engineering by Christopher D. Rahn