By Xiao-Ming Jiang, Sheng-Ping Guo, Hui-Yi Zeng (auth.), Xin-Tao Wu, Ling Chen (eds.)
ISBN-10: 3642296203
ISBN-13: 9783642296208
ISBN-10: 3642296211
ISBN-13: 9783642296215
Xiao-Ming Jiang, Sheng-Ping Guo, Hui-Yi Zeng, Ming-Jian Zhang, Guo-Cong Guo: huge Crystal development and New Crystal Exploration of Mid-Infrared Second-Order Nonlinear Optical Materials.- Kechen Wu: Simulation and layout of Infrared Second-Order Nonlinear Optical fabrics in steel Cluster Compounds.- Chaoyang Tu: the new improvement Of SRS and SRS SF- conversion Laser Crystal.- Hua-Jun Zhao, Xin-Tao Wu, Li-Ming Wu: Exploration of recent Second-Order Nonlinear Optical Compounds Containing major staff Elements.
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Extra resources for Structure-Property Relationships in Non-Linear Optical Crystals II: The IR Region
Example text
The chains have Zr4+ ions coordinated with Se atoms in a distorted bicapped trigonal prismatic geometry (Fig. 11c). All Zr4+ ions are connected to a 11[PSe3À] polymeric backbone formed by the condensation of corner-sharing tetrahedral PSe4 units (Fig. 11b). Each phosphorus atom has a terminal P–Se bond projecting out from the one-dimensional chain structure. The Zr atoms are also bridged with Z4-bonded Se22À groups. Finally, there is also terminal Se(3) atom on each zirconium metal center. The polar structure and presence of highly polarizable atoms such as Se, Rb, Cs, and Zr result in their strong SHG response.
M. Jiang et al. Fig. 13 View of 3-D cationic host (Hg6P3)3+ framework and discrete guest (In2Cl9)3À anions of (Hg6P3)(In2Cl9) along the b direction (a left), isolated (In2Cl9)3À anions are embedded in the helical channels of the host framework (a right). Three-dimensional cationic host (Hg8As4)4+ framework and 11(Bi3Cl13)4À helical chain of (Hg8As4)(Bi3Cl13) along the c direction (b left), 4À 1 helical chain embed in the channel of the host framework (b right) 1 (Bi3Cl13) designed in a reasonable alignment to enforce macroscopic dipole ordering efficiently through crystal engineering strategy [45].
Experimental SHG gave the d31 coefficient of 29 pm/V for the both compositions. 06-mm pump wavelength. 06-mm conversion to mid-IR and far-mid regions. -M. Jiang et al. Fig. 4 (a) View of the Li2Ga2GeS6 structure parallel to [001]. (b) View of the structure of Li2Ga2GeS6 projected onto the (101) emphasizing GaS4 chains. (c) View of the structure on to the (110) plane emphasizing the lithium tetrahedral chains. Adapted with permission from [54]. Copyright # 2008 American Chemical Society because of the possibility of increased laser-damage thresholds.
Structure-Property Relationships in Non-Linear Optical Crystals II: The IR Region by Xiao-Ming Jiang, Sheng-Ping Guo, Hui-Yi Zeng (auth.), Xin-Tao Wu, Ling Chen (eds.)
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